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[Lab on a chip] Modeling electrical double-layer effects for microfluidic impedance spectroscopy fro


Broadband microfluidic-based impedance spectroscopy can be used to characterize complex fluids, with applications in medical diagnostics and in chemical and pharmacological manufacturing. Many relevant fluids are ionic; during impedance measurements ions migrate to the electrodes, forming an electrical double-layer. Effects from the electrical double-layer dominate over, and reduce sensitivity to, the intrinsic impedance of the fluid below a characteristic frequency. Here we use calibrated measurements of saline solution in microfluidic coplanar waveguide devices at frequencies between 100 kHz and 110 GHz to directly measure the double-layer admittance for solutions of varying ionic conductivity. We successfully model the double-layer admittance using a combination of a Cole–Cole response with a constant phase element contribution. Our analysis yields a double-layer relaxation time that decreases linearly with solution conductivity, and allows for double-layer effects to be separated from the intrinsic fluid response and quantified for a wide range of conducting fluids.

Charles A. E. Little,ab Nathan D. Orloff,b Isaac E. Hanemann,c Christian J. Long,b Victor M. Brighta and James C. Booth*b Author affiliations * Corresponding authors a Department of Mechanical Engineering, University of Colorado, Boulder, USA b Communications Technology Laboratory, National Institute of Standards and Technology, Boulder, USA E-mail: james.booth@nist.gov c Department of Physics, University of Colorado, Boulder, USA

Link: http://pubs.rsc.org/en/Content/ArticleLanding/2017/LC/C7LC00347A#!divAbstract

#07152017 #spectroscopy

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